Chemistry Timeline

Robert Millikan 1868-1953AD

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Robert Millikan 1868-1953AD
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Erwin Schrödinger 1887-1961 AD
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Discovery:

            Robert Millikan measured the charge on an electron in 1909.

           

 

Experiment:

            The Oil-Drop Experiment

 

The scheme of the experiment is as follows: An atomizer sprayed a fine mist of oil droplets into the upper chamber. Some of these tiny droplets fell through a hole in the upper floor. Millikan first let them fall until they reached terminal velocity due to air resistance. Using the microscope, he measured their terminal velocity, and by use of a formula, calculated the mass of each oil drop.

 

Next, Millikan applied a charge to the falling drops by irradiating the bottom chamber with x-rays. This caused the air to become ionized, which basically means that the air particles lost electrons. A part of the oil droplets captured one or more of those extra electrons and became negatively charged.

 

By attaching a battery to the plates he created an electric field between the plates that would act on the charged oil drops; he adjusted the voltage till the electric field force would just balance the force of gravity on a drop, and the drop would hang suspended in mid-air. Some drops have more captured electrons than others, so they will require a higher electrical field to stop.

 

Particles that did not capture any of that extra electrons were not affected by the electrical field and fell to the bottom plate due to gravity.

 

When a drop is suspended, its weight m ˇ g is exactly equal to the electric force applied, the product of the electric field and the charge - q ˇ E

 

The Oil-Drop Experiment Apparatus

 

The values of E, the applied electric field, m the mass of a drop, and g, the acceleration due to gravity, are all known values. So it is very easy to obtain the value of q, the charge on the drop.

 

Millikan repeated the experiment numerous times, each time varying the strength of the x-rays ionizing the air, so that differing numbers of electrons would jump onto the oil molecules each time. He obtained various values for q.

 

The charge q on a drop was always a multiple of 1.59 x 10-19 Coulombs. This is less than 1% lower than the value accepted today: 1.602 x 10-19 C.

 

 

Event:

            January 1953

 

Wednesday 07:

 

President Harry Truman announces that the United States has developed a hydrogen bomb.

 

Thursday 08:

 

René Mayer becomes Prime Minister of France.

 

Tuesday 13:

 

Marshal Josip Broz Tito chosen President of Yugoslavia.

 

Monday 19:

 

68% of all United States television sets were tuned in to I Love Lucy to watch Lucy give birth.